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Drawing and ultimate tenacity properties of polyamide 6/attapulgite composite fibers
Author(s) -
Tsai FangChang,
Li Peng,
Liu ZhiWei,
Feng Gang,
Zhu Ping,
Wang ChuenKai,
Chen KanNan,
Huang ChiYuan,
Yeh Jentaut
Publication year - 2012
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.36970
Subject(s) - materials science , crystallinity , polyamide , composite material , composite number , fourier transform infrared spectroscopy , fiber , tenacity (mineralogy) , nanofiber , polymer chemistry , chemical engineering , engineering
The drawing and ultimate tenacity properties of the Polyamide 6 (PA6)/Attapulgite (ATP) composite fiber specimens prepared at varying modified ATP (mATP) contents and drawing condition were systematically investigated. As evidenced by Fourier transform infrared (FTIR) and morphological analysis, demarcated translucent resins were found firmly attached on the surfaces of ATP nanofibers. The specific surface areas of the mATP specimens reached a maximum value at 381 m 2 /g as the weight ratios of silane coupling agents to ATP nanofibers reached an optimum value at 1.0. The percentage crystallinity and melt shear viscosity values measured at varying shear rates of PA6 x (mATP) y specimens increased consistently as their mATP contents increased. In contrast, melting temperatures of PA6 x (mATP) y specimens reduced slightly as their mATP contents increased. At a fixed drawing temperature and rate, the achievable draw ratio ( D ra ) values of PA6 x (mATP) y as‐spun fiber specimens approach a maximum value, as their mATP contents are close to the 0.2 wt % optimum value. The maximum D ra values obtained for PA6 99.8 (mATP) 0.2 as‐spun fiber specimens reached another maximum, when their drawing temperatures and rates approached the optimum values at 120°C and 50 mm/min, respectively. At a fixed draw ratio, the tenacity values of PA6 x (mATP) y drawn fiber specimens drawn at the optimum drawing temperature and rate reached a maximum value, as their mATP contents approached the 0.2 wt % optimum value. Possible reasons accounting for the interesting morphological, specific surface area, drawing, orientation, and ultimate tenacity properties found for the PA6 x (mATP) y fiber specimens are proposed. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012