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Foaming of recycled crosslinked polyethylenes via supercritical decrosslinking reaction
Author(s) -
Kwon Yong Jin,
Park Wan Yong,
Hong Soon Man,
Koo Chong Min
Publication year - 2012
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.36617
Subject(s) - polyolefin , polyethylene , materials science , supercritical fluid , low density polyethylene , composite material , polypropylene , chemical engineering , polymer chemistry , chemistry , organic chemistry , layer (electronics) , engineering
Abstract Foaming of decrosslinked crosslinked polyethylene (DCXLPE) was investigated to assess the feasibility of recycled crosslinked polyethylene for polyolefin foam applications. DCXLPE was recycled from irradiation‐induced crosslinked polyethylene using the supercritical methanol process. As the concentration of crosslinking agents increased, the gel fraction and hardness of the DCXLPE foam sheets increased, while the expansion ratio and cell size decreased. The resulting foam products not only revealed a viable foam structure and properties comparable with those of conventional polyethylene foam from virgin low‐density polyethylene resin but also are expected to open new applications for recycled crosslinked polyolefin via supercritical decrosslinking reaction. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012