Functional terpolymers containing vinylphosphonic acid: The synthesis and characterization of poly(vinylphosphonic acid‐ co ‐styrene‐ co ‐maleic anhydride) | Zendy

Kavlak Serap | Zendy; Güner Ali | Zendy; Rzayev Zakir M. O. | Zendy

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Functional terpolymers containing vinylphosphonic acid: The synthesis and characterization of poly(vinylphosphonic acid‐ co ‐styrene‐ co ‐maleic anhydride)

Author(s) -

Kavlak Serap,

Güner Ali,

Rzayev Zakir M. O.

Publication year - 2012

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.36522

Subject(s) - polymer chemistry , copolymer , monomer , chemistry , maleic anhydride , polymerization , polymer , organic chemistry

Novel functional temperature‐sensitive amphiphilic P‐containing polymers were synthesized by complex‐radical ternary polymerization of vinylphosphonic acid (VPA), styrene (S), and maleic anhydride (MA). Charge transfer complexes (CTCs), complex‐formation constants ( K c ) between acceptor and donor monomer systems and the complexed monomer reactivity ratios were investigated by 1 H‐NMR analysis. Contrary to theoretical predictions, the VPA…S complex is more active as compared to MA…S complex in the ternary system since VPA monomer can form the CTC both with S monomer and strong H‐bonded complex with MA monomer. The terpolymer compositions, characterizations, and structure–property relationships of a series of poly(VPA‐ co ‐S‐ co ‐MA)s were investigated by GPC, FTIR, Raman, 1 H‐NMR, 13 C‐NMR, DEPT‐135, 31 P‐NMR, TGA‐DSC, DMA, XRD, viscometry, and titration. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

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