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Colloidal and polymer properties difference of fluorinated acrylate latex prepared with different fluorinated monomers
Author(s) -
Chen Lijun,
Wu Fengqin
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.35592
Subject(s) - materials science , polymer chemistry , acrylate , potassium persulfate , monomer , methacrylate , glass transition , butyl acrylate , methyl methacrylate , acrylate polymer , polymer , differential scanning calorimetry , contact angle , copolymer , ethyl acrylate , chemical engineering , composite material , physics , engineering , thermodynamics
Fluorinated acrylate latex was prepared by copolymerizing fluorinated monomer, butyl acrylate, and methyl methacrylate, which was initiated by potassium persulfate in the water. The resultant fluorinated latex and its film were characterized with contact angle determinator, dynamic light scattering detector, and differential scanning calorimetry, respectively. Influence of type of fluorinated monomers on colloidal and polymer properties of fluorinated acrylate latex was studied. Results show that the coagulation rate, particle size, contact angle, glass transition temperature, and chemical resistance are increased with the increase of the number of fluorine atom in the fluorinated monomer. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012