Premium
Preparation of novel nano/submicrofiber catalyst containing nano‐TiO 2 particles
Author(s) -
Liu Taiqi,
Lv Dan,
Cao Binbin,
Wang Hongtao
Publication year - 2012
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.35577
Subject(s) - materials science , nano , chemical engineering , anatase , electrospinning , scanning electron microscope , dispersity , fourier transform infrared spectroscopy , catalysis , particle size , particle (ecology) , composite material , polymer , polymer chemistry , photocatalysis , chemistry , organic chemistry , oceanography , geology , engineering
A novel Nano/submicrofiber catalyst was prepared via electrospinning technology from poly (vinyl pyrrolidone) (PVP) and nano‐TiO 2 . First, nano‐TiO 2 particles were added into the mixture of ethanol and deionized water, the mass ratio of ethanol and deionized water was 1 : 1, the TiO 2 suspension was obtained after 1 h with ultrasonic treatment and centrifugal effect, Then PVP was added into the above‐mentioned suspension and the content of PVP in the sol was 28%. The TiO 2 /PVP solution was electrospun with different voltage. The effects of the content of TiO 2 and electrospinning voltage on diameter of nano/submicrofiber were studied. The nano/submicrofiber catalyst was characterized by scanning electron microscopy, transmission electron microcopy, X‐ray diffraction, and Fourier transform infrared. The results show that the diameter of nano/submicrofiber increases with an increase of the content of nano‐TiO 2 and decreases with the increase of electrospinning voltage. The analytical result showed that the nano‐TiO 2 particles were well dispersed in the matrix of PVP, moreover, the crystal type of nano‐TiO 2 was a mixture of anatase and rutile and the diameter of nano‐TiO 2 particles in the nano/submicrofiber is in the range of 20–60 nm and the nano‐TiO 2 particle was monodisperse, and the nano‐TiO 2 particle and PVP molecule was connected by a hydrogen bonding. This nano/submicrofiber catalyst has a high efficiency on degradation on CH 2 O. 56.8 percent of CH 2 O was degraded under ultraviolet radiation in 80 min when the content of nano‐TiO 2 is 20% in nano/submicrofibers. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012