Premium
Thermal and mechanical properties of LDPE/sisal fiber composites compatibilized with functionalized paraffin waxes
Author(s) -
Nhlapo L. P.,
Luyt A. S.
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.35023
Subject(s) - low density polyethylene , materials science , wax , composite material , differential scanning calorimetry , sisal , ultimate tensile strength , thermal stability , crystallization , paraffin wax , maleic anhydride , polyethylene , polymer , copolymer , chemistry , organic chemistry , physics , thermodynamics
The effect of maleic anhydride‐grafted hard paraffin wax (MA‐ g ‐wax) and oxidized hard paraffin wax (OxWax), as possible compatibilizers, on the morphology, thermal and mechanical properties of LDPE/sisal fiber composites were examined. The differential scanning calorimetry (DSC) results show that sisal alone did not change the crystallization behavior of LDPE, while the two waxes influenced the crystallization behavior of LDPE in different ways, whether mixed with LDPE alone or in the presence of sisal. The thermal properties seem to be influenced by the fact that the waxes preferably crystallize around the short sisal fibers, and by the fact that the two waxes have different compatibilities with LDPE. The TGA results show an increase in the thermal stability of the blends in the presence of the two waxes, with LDPE/OxWax showing a more significant improvement. The presence of wax, however, reduced the thermal stability of the LDPE/sisal/wax composites. The presence of OxWax and MA‐ g ‐wax similarly influenced the tensile properties of the composites. Both waxes similarly improved the modulus of the compatibilized composites, but in both cases the tensile strengths were worse, probably because of a fairly weak interaction between LDPE and the respective waxes. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012