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Polymerization of 3‐glycidyloxypropyltrimethoxysilane with different catalysts
Author(s) -
Kayan Asgar
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34859
Subject(s) - polymerization , potassium hydroxide , gel permeation chromatography , polymer chemistry , electrospray ionization , fourier transform infrared spectroscopy , chemistry , tetraphenylporphyrin , catalysis , infrared spectroscopy , mass spectrometry , nuclear chemistry , polymer , materials science , organic chemistry , chemical engineering , chromatography , porphyrin , engineering
Abstract Polymerization reactions of 3‐glycidyloxypropyltrimethoxysilane (GPTS) were carried out by different catalysts, potassium hydroxide, potassium tert ‐butoxide, and tetraphenylporphyrin aluminum chloride (TPP–AlCl), and tetrafluorophthalate zironium isopropoxide complex. Polymer samples obtained from the ring‐opening polymerization of GPTS were characterized by Fourier transform infrared spectroscopy, NMR spectroscopy, electrospray ionization mass spectroscopy, and gel permeation chromatography. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012