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Preparation and characterization of the structure of PSt‐ b ‐PAA/Co composite material
Author(s) -
Yang Runmiao,
Dong Guanxiu,
Liu Yuhai,
Sun Jianhua,
Xu Yangyang
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34803
Subject(s) - materials science , polymer , copolymer , polystyrene , composite number , dispersity , nanoparticle , polyacrylic acid , chain transfer , composite material , nanocomposite , polymer chemistry , polymerization , chemical engineering , radical polymerization , nanotechnology , engineering
The polystyrene‐ block ‐polyacrylic acid (PSt‐ b ‐PAA) copolymer is obtained through the reversible addition‐fragmentation chain transfer polymerization (RAFT). Then the cobalt (Co) nano‐particles are synthesized by loading the Co 2+ salt into the polymer and reducing them. Polymer–matrix composites with an average particle size of 10 nm have been formed by a simple technique. The technique exploits the dispersed phase of the polymer to form numerous identical nanoreactors. In this approach, nanoparticles are rigidly attached to the support surface to prevent their agglomeration. FT‐IR and TEM analysis of these polymer–matrix composites revealed that nano‐structures are formed and the shape can be controlled. Vibrating sample magnetometer is also used to study the magnetic property of the materials at room temperature. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012