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Effect of elastic properties modification on the vibrational density of states: A joint Brillouin and Raman scattering study
Author(s) -
Caponi S.,
Corezzi S.,
Fioretto D.,
Fontana A.,
Rossi F.
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34780
Subject(s) - elastic modulus , materials science , brillouin scattering , brillouin zone , raman spectroscopy , raman scattering , molecular physics , isothermal process , light scattering , scattering , thermodynamics , condensed matter physics , optics , chemistry , composite material , physics , laser
The modification of the vibrational density of states in a reactive epoxy–amine mixture during isothermal polymerization at different temperatures was characterized by Brillouin and Raman scattering measurements. During the reaction, the system underwent the glass‐transition passing from the liquid to the glassy phase. The relative variations of the boson peak (BP) and the elastic moduli were investigated. We found that the intensity variation and the shift of the BP could be completely explained in terms of the elastic medium transformation. A master curve of the spectra in the BP region can always be obtained both as a function of the reaction temperature and as a function of the reaction time. Moreover, the Brillouin light‐scattering results gave evidence of the validity of a Cauchy‐like relation for the real part of the elastic moduli measured at finite frequencies also in a relaxing regime. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011