Compatibilizer in waste tire powder and low‐density polyethylene blends and the blends modified asphalt

With the increasing ratio of waste tire powder (WTP) to low‐density polyethylene (LDPE), the hardness and tensile strength of the WTP/LDPE blends decreased while the elongation at break increased. Five kinds of compatibilizers, such as maleic anhydride‐grafted polyethylene (PE‐ g ‐MA), maleic anhydride‐grafted ethylene‐octene copolymer (POE‐ g ‐MA), maleic anhydride‐grafted linear LDPE, maleic anhydride‐grafted ethylene vinyl‐acetate copolymer, and maleic anhydride‐grafted styrene‐ethylene‐butylene‐styrene, were incorporated to prepare WTP/LDPE blends, respectively. PE‐ g ‐MA and POE‐ g ‐MA reinforced the tensile stress and toughness of the blends. The toughness value of POE‐ g ‐MA incorporating blends was the highest, reached to 2032.3 MJ/m 3 , while that of the control was only 1402.9 MJ/m 3 . Therefore, POE‐ g ‐MA was selected as asphalt modifier. The toughness value reached to the highest level when the content of POE‐ g ‐MA was about 8%. Besides that the softening point of the modified asphalt would be higher than 60°C, whereas the content of WTP/LDPE blend was more than 5%, and the blends were mixed by stirring under the shearing speed of 3000 rpm for 20 min. Especially, when the blend content was 8.5%, the softening point arrived at 82°C, contributing to asphalt strength and elastic properties in a wide range of temperature. In addition, the swelling property of POE‐ g ‐MA/WTP/LDPE blend was better than that of the other compalibitizers, which indicated that POE‐ g ‐MA /WTP/LDPE blend was much compatible with asphalt. Also, the excellent compatibility would result in the good mechanical and processing properties of the modified asphalt. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011