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Synthesis, characterization, and ion exchange voltammetry study on 2‐acrylamido‐2‐methylpropane sulphonic acid and N ‐(hydroxymethyl) acrylamide‐based copolymer
Author(s) -
Rastogi Pankaj Kumar,
Krishnamoorthi S.,
Ganesan Vellaichamy
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34538
Subject(s) - copolymer , hydroxymethyl , polymer chemistry , sulfonic acid , ceric ammonium nitrate , acrylamide , cyclic voltammetry , polymerization , materials science , ammonium persulfate , fourier transform infrared spectroscopy , chemistry , chemical engineering , polymer , organic chemistry , electrochemistry , electrode , composite material , engineering
A random copolymer of 2‐acrylamido‐2‐methylpropane sulfonic acid (AMPS) and N ‐hydroxymethyl acrylamide (NHMA) was prepared by solution polymerization using ceric ammonium nitrate as an initiator. A grade of poly(AMPS)‐ co ‐poly(NHMA) (PAMPS‐ co ‐PNHMA) random copolymer was synthesized with AMPS and NHMA. The homopolymerization of AMPS and NHMA was also carried out by the same way as that of random copolymer. PAMPS‐ co ‐PNHMA and homopolymers of AMPS and NHMA were characterized by FTIR, rheology, FT‐NMR, scanning electron microscope, thermal analysis, and X‐ray diffaractometry. Cyclic voltammetry is used to explain the ion exchange properties of PAMPS‐ co ‐PNHMA and its possible application in the trace analysis. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011