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Investigation of liquefied wood residues based on cellulose, hemicellulose, and lignin
Author(s) -
Zhang HaiRong,
Pang Hao,
Shi Jingzhi,
Fu TieZhu,
Liao Bing
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34521
Subject(s) - hemicellulose , lignin , liquefaction , cellulose , chemistry , organic chemistry , yield (engineering) , solvent , ethylene glycol , glycerol , nuclear chemistry , materials science , composite material
Chinese eucalyptus was subjected to a liquefaction process using glycerol/ethylene glycol (EG) as liquefaction solvent. The effects of various liquefaction conditions, including reaction time, liquefaction temperature, acid concentration, and liquor ratio on the chemical composition of liquefied wood residues were studied. The results showed that the whole liquefaction process took place in two stages, the liquefaction yield of wood depended on the reaction temperature, acid concentration and liquor ratio. With increased acid concentration the liquefaction yield, acid‐insoluble lignin, and hemicellulose content of the residues were increased, and the relative content of cellulose was decreased. Fourier transform infrared (FT‐IR) analyses of the residues showed that hemicellulose and lignin were almost decomposed at the initial stages of reaction. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011