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Studies on synthesis and physicochemical properties of new bis[4‐(2‐hydroxy‐3‐methacryloyloxypropoxy)phenyl]sulfide terpolymers
Author(s) -
Podkościelna Beata,
Maciejewska Małgorzata,
Bartnicki Andrzej
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34487
Subject(s) - diethylenetriamine , thermogravimetric analysis , glycidyl methacrylate , polymer chemistry , copolymer , sulfide , swelling , epoxide , materials science , styrene , suspension polymerization , polymerization , thermal stability , epoxy , methacrylate , chemical engineering , chemistry , organic chemistry , catalysis , polymer , composite material , engineering , metallurgy
Synthesis and physicochemical properties of the new glycidyl methacrylate, styrene, and bis[4(2‐hydroxy‐3‐methacryloyloxypropoxy)phenyl]sulfide terpolymers of different crosslinking degrees are presented. The terpolymers were obtained in the form of regular microspheres by suspension polymerization. The epoxy group content, thermal properties (DSC, thermogravimetric analysis), and swelling characteristic of the functional microspheres were examined. In addition, a selected terpolymer was modified in the epoxide ring opening reaction with diethylenetriamine. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011