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Isothermal crystallization kinetics and melting behavior of polyamide 11/silica nanocomposites prepared by in situ melt polymerization
Author(s) -
Zhang Yunsheng,
Wang Biaobing,
Hu Guosheng
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34481
Subject(s) - materials science , differential scanning calorimetry , nucleation , crystallization , kinetics , polyamide , polymerization , avrami equation , isothermal process , polymer chemistry , melting point , nanocomposite , in situ polymerization , chemical engineering , polymer , thermodynamics , composite material , enthalpy of fusion , physics , quantum mechanics , engineering
Polyamide 11 (PA 11)/silica nanocomposites were prepared via in situ melt polymerization by the dispersion of hydrophobic silica in 11‐aminoundecanoic acid monomer. Their isothermal crystallization process and melting behaviors were analyzed by differential scanning calorimetry. The isothermal crystallization kinetics was analyzed by the Avrami equation. The obtained data showed that the model of nucleation and growth of PA 11 was not affected after the incorporation of silica and was a mixture with two‐dimensional, circular, three‐dimensional growth with thermal nucleation. Double and single melting peaks were observed depending on the crystallization temperature. The equilibrium melting point of samples was evaluated, and the spherulites growth kinetics parameters and fold surface free energy were further calculated according to the classical theories. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011