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Thermal properties of polyurethane binder with 2‐(ferrocenylpropyl)dimethylsilane‐grafted hydroxyl‐terminated polybutadiene
Author(s) -
Cho BongSang,
Noh SiTae
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.34151
Subject(s) - polyurethane , dimethylsilane , polybutadiene , materials science , hydroxyl terminated polybutadiene , differential scanning calorimetry , trimer , polymer chemistry , fourier transform infrared spectroscopy , composite material , chemical engineering , copolymer , chemistry , organic chemistry , polymer , dimer , physics , engineering , thermodynamics
We synthesized a ferrocene‐based burning rate catalyst, 2‐(ferrocenylpropyl) dimethylsilane (FPDS). FPDS‐grafted hydroxyl‐terminated polybutadiene (FPDS‐ g ‐HTPB) was synthesized using hydrosilylation with a Pt catalyst. The structures of FPDS and FPDS‐ g ‐HTPB were investigated by Fourier transform infrared spectroscopy and nuclear magnetic resonance. HTPB‐based polyurethanes were prepared from HTPB, 6‐hexamethylenediisocyanate (HDI), and HDI‐trimer. Polyurethane network was prepared with an (NCO)/(OH) ratio of 1.05 and an [isocyanate trimer]/[total NCO] ratio of 0.3 then subjected to accelerated aging at 80°C. The thermal behaviors of the polyurethane network were compared using differential scanning calorimetry and thermal gravity analysis. The glass transition temperatures ( T g ) of HTPB and FPDS‐ g ‐HTPB were −76°C and −47°C, respectively. The value of T g for the networked polyurethane was not influenced by HDI‐trimer content but by FPDS content. The decomposition temperature of the neat HTPB‐based polyurethane network was lower than that of the FPDS‐ g ‐HTPB‐based polyurethane networks. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011