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Dynamic rheology and morphology of polylactide/organic montmorillonite nanocomposites
Author(s) -
Wang Biao,
Wan Tong,
Zeng Wei
Publication year - 2011
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.33717
Subject(s) - rheology , materials science , montmorillonite , nanocomposite , composite material , shear thinning , transmission electron microscopy , morphology (biology) , nanotechnology , biology , genetics
The effects of organic montmorillonite (OMMT) on the rheological behaviors and phase morphology of polylactide (PLA) were investigated. The rheological behaviors of nanocomposites showed mainly dependence on both temperature and OMMT content. At low OMMT loading (1 wt %), the complex viscosities showed a Newtonian plateau in low frequency region at low temperatures and converted to a shear‐thinning behaviors with increasing temperature. In comparison, at high OMMT loadings (above 5 wt %), strong shear‐thinning behaviors were observed in the full range of frequencies and temperatures. The results demonstrated rheology of PLA/OMMT is highly sensitive to the nanofillers filled materials. A pseudo‐solid‐like behavior at long scale time in the hybrids with OMMT loading was higher than 5 wt %, this response was related to the formation of a network structure across the polymer matrix due to strong interactions of PLA and OMMT that confined the relaxation process of the macromolecules. X‐ray diffraction and transmission electron microscopy indicated the nanocomposites at low OMMT loading were mainly exfoliated and intercalated nanocomposites were gradually formed with increasing OMMT loading. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011