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A fast method to assess the composition of a polyolefin: An application to compliance testing of food contact materials
Author(s) -
Gillet Guillaume,
Vitrac Olivier,
Desobry Stéphane
Publication year - 2010
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.32950
Subject(s) - polyolefin , food contact materials , tikhonov regularization , deconvolution , computer science , identification (biology) , work (physics) , process engineering , polymer , polycarbonate , biological system , algorithm , materials science , biochemical engineering , mathematics , food packaging , thermodynamics , mechanical engineering , nanotechnology , composite material , physics , inverse problem , engineering , mathematical analysis , botany , layer (electronics) , biology
Abstract For plastics materials intended to be in contact with food, recent EU regulations, 72/2002/EC and 1935/2004/EC, enforce the assessment of the migration of 502 substances of the 932 positively listed substances. As mathematical modeling has been proposed to overcome such considerable effort in particular by providing maximum acceptable concentrations in the formulation, the compliance testing problem is efficiently reduced to the identification of substances and to their extent in initial materials. This work examines a fast identification and quantification procedure based on a semisupervised deconvolution procedure of FTIR spectra of polymer extracts in dichloromethane. The inversion procedure was implemented as a Tikhonov least‐square problem and designed to work on large and open dictionary of substances by combining both spectra of reference additives and normalized responses of typical chemical functions. The sparsity of the overall solution was fulfilled with non‐negativity constraints, while traces were detected by an iterative reweighting and stochastic resonance. The whole methodology was calibrated onto 21 typical additives of polyolefins and satisfactory tested on numerical examples and on extracts of processed films in high‐density polyethylene including up to eight unknown compounds. Maps of possible confusions and biases were generated for all tested substances. The mass balance laws for molecules belonging to similar classes of additives were particularly highlighted. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011