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Synthesis of poly( D , L ‐lactic acid) modified by triethanolamine by direct melt copolycondensation and its characterization
Author(s) -
Luo YuFen,
Wang ZhaoYang,
Ye RuiRong,
Luo ShiHe,
Yang LiTing
Publication year - 2010
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.32900
Subject(s) - triethanolamine , gel permeation chromatography , fourier transform infrared spectroscopy , differential scanning calorimetry , materials science , lactic acid , condensation polymer , nuclear chemistry , polymer chemistry , copolymer , molar mass , polymer , chemical engineering , chemistry , organic chemistry , composite material , analytical chemistry (journal) , physics , genetics , biology , bacteria , engineering , thermodynamics
Using D , L ‐lactic acid (LA) and multifunctional group compound triethanolamine (TEA) as starting materials, a novel biodegradable material poly( D , L ‐lactic acid‐triethanolamine) [P(LA‐TEA)] was directly synthesized by simpler and practical melt polycondensation. The appropriate synthetic condition was discussed in detail. When the molar feed ratio LA/TEA was 30/1, the optimal synthesis conditions were as follows: a prepolymerization time of 12 h; 0.5 weight percent (wt %) SnO catalyst; and melt copolycondensation for 8 h at 160°C, which gave a novel star‐shaped poly( D,L ‐lactic acid) (PDLLA) modified by TEA with the maximum intrinsic viscosity [η] 0.93 dL g −1 . The copolymer P(LA‐TEA) as a different molar feed ratio was characterized by [η], Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance ( 1 H‐NMR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and X‐ray diffraction (XRD). Increasing the molar feed ratio of LA/TEA, T g and M w increased. However, all copolymers were amorphous, and their T g (12.2°C–32.5°C) were lower than that of homopolymer PDLLA. The biggest M w was 9400 Da, which made the biodegradable polymer be potentially used as drug delivery carrier, tissue engineering material, and green finishing agent in textile industry. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011