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Miscibility enhancement through hydrogen bonding interaction of biodegradable poly(3‐hydroxybutyrate) blending with poly(styrene‐ co ‐vinyl phenol) copolymer
Author(s) -
Kuo ShiaoWei,
Liu WeiChen
Publication year - 2010
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.32528
Subject(s) - miscibility , copolymer , polymer chemistry , fourier transform infrared spectroscopy , differential scanning calorimetry , materials science , styrene , hydrogen bond , phenol , polymer , chemical engineering , chemistry , organic chemistry , molecule , composite material , thermodynamics , physics , engineering
Differential scanning calorimetry, one‐ and two‐dimensional Fourier transform infrared (FTIR), and solid state nuclear magnetic resonance (NMR) spectroscopy have been used to investigate the miscibility of and specific interactions between poly(styrene‐ co ‐vinyl phenol) (PSOH) and poly(3‐hydroxybutyrate) (PHB) upon varying the vinyl phenol content of the PSOH copolymer. The FTIR and solid state NMR spectra revealed that the phenol units of PVPh interact with the carbonyl groups of PHB through intermolecular hydrogen bonding. A miscibility window exists when the vinyl phenol fraction in the copolymer is greater than 22 mol % in the PSOH/PHB blend system, as predicted using the Painter–Coleman association model. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011