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Preparation and properties of the single‐walled carbon nanotube/cellulose nanocomposites using N ‐methylmorpholine‐ N ‐oxide monohydrate
Author(s) -
Kim DongHun,
Park SooYoung,
Kim Junkyung,
Park Min
Publication year - 2010
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.32247
Subject(s) - materials science , nanocomposite , cellulose , carbon nanotube , lyocell , composite material , oxide , ultimate tensile strength , chemical engineering , fiber , engineering , metallurgy
Single‐walled carbon nanotube (SWNT)/cellulose nanocomposite films were prepared using N ‐methylmorpholine‐ N ‐oxide (NMMO) monohydrate as a dispersing agent for the acid‐treated SWNTs (A‐SWNTs) as well as a cellulose solvent. The A‐SWNTs were dispersed in both NMMO monohydrate and the nanocomposite film (as confirmed by scanning electron microscopy) because of the strong hydrogen bonds of the A‐SWNTs with NMMO and cellulose. The mechanical properties, thermal properties, and electric conductivity of the nanocomposite films were improved by adding a small amount of the A‐SWNTs to the cellulose. For example, by adding 1 wt % of the A‐SWNTs to the cellulose, tensile strain at break point, Young's modulus, and toughness increased ∼ 5.4, ∼ 2.2, and ∼ 6 times, respectively, the degradation temperature increased to 9°C as compared with those of the pure cellulose film, and the electric conductivities at ϕ (the wt % of A‐SWNTs in the composite) = 1 and 9 were 4.97 × 10 −4 and 3.74 × 10 −2 S/cm, respectively. Thus, the A‐SWNT/cellulose nanocomposites are a promising material and can be used for many applications, such as toughened Lyocell fibers, transparent electrodes, and soforth. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010