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Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior
Author(s) -
Govorčin Bajsić Emi,
Pustak Anđela,
Šmit Ivan,
Leskovac Mirela
Publication year - 2010
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.31997
Subject(s) - thermoplastic polyurethane , crystallinity , polypropylene , materials science , differential scanning calorimetry , spherulite (polymer physics) , crystallization , composite material , thermoplastic elastomer , polymer blend , elastomer , scanning electron microscope , phase inversion , polymer chemistry , polymer , chemical engineering , copolymer , chemistry , membrane , biochemistry , physics , engineering , thermodynamics
Neat thermoplastic polyurethane (TPU), polypropylene (PP), and TPU/PP blends with different weight ratios that were prepared in a twin‐screw extruder were investigated with differential scanning calorimetry and light and scanning electron microscopy. The results confirmed PP matrix to TPU matrix phase inversion in the concentration region between 60/40 and 80/20 TPU/PP blends. The total degree of crystallinity of the blends and the crystallization temperature of PP decreased with increasing TPU content. On the other hand, the addition of elastomeric TPU to PP significantly increased the spherulite size of PP. The TPU melt islands in the PP matrix prolonged the crystallization of PP during solidification, and this enhanced the growth of spherulites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010