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Thermal, morphological, and mechanical characterization of novel carbon nanofiber‐filled bismaleimide composites
Author(s) -
Faraz M. I.,
Bhowmik S.,
De Ruijter C.,
Laoutid F.,
Benedictus R.,
Dubois Ph.,
Page J. V. S.,
Jeson S.
Publication year - 2010
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.31842
Subject(s) - materials science , composite material , dynamic mechanical analysis , thermogravimetric analysis , thermal stability , nanocomposite , limiting oxygen index , carbon nanofiber , scanning electron microscope , dispersion (optics) , glass transition , nanofiber , fiber , carbon nanotube , polymer , chemical engineering , pyrolysis , char , physics , optics , engineering
Novel carbon nanofiber (CNF) ‐filled bismalemide composites were fabricated by a thermokinetic mixing method. The thermal and mechanical properties of composites containing 1 wt % and 2 wt % CNFs were investigated. Thermogravimetric analysis demonstrated that minimal improvement in thermal stability of the nanocomposites was obtained by the addition of CNFs. Dynamic mechanical analysis showed an increase in storage modulus ( E ′) and glass transition temperature ( T g ) upon incorporation of nanofibers. Limiting oxygen index (LOI) has also been found to increase with incorporation of CNFs. Morphological studies of fractured surfaces of the composites has been carried out by scanning electron microscopy to determine the effect of fiber content and dispersion on the failure mechanism. In general, good dispersion was observed, along with agglomeration at some points and some fiber matrix interfacial debonding. A decrease in mechanical strength has been observed and debonding was found as the main failure mechanism. Further research outlook is also presented. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010