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Nanocomposites of poly(vinylidene fluoride) with multiwalled carbon nanotubes
Author(s) -
Huang Wenwen,
Edenzon Kyle,
Fernandez Luis,
Razmpour Shabnam,
Woodburn Jenna,
Cebe Peggy
Publication year - 2009
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.31393
Subject(s) - materials science , crystallinity , nanocomposite , glass transition , differential scanning calorimetry , composite material , carbon nanotube , dynamic mechanical analysis , fourier transform infrared spectroscopy , crystallization , thermal stability , polymer , chemical engineering , physics , engineering , thermodynamics
Abstract The preparation and characterization of nanocomposites of poly(vinylidene fluoride), PVDF, with acid treated multiwalled carbon nanotubes (MWCNT) with a wide composition range, from 0.1 to 5.0% MWCNT by weight, is reported. Effect of uniaxial orientation by zone drawing on these nanocomposites is discussed and compared with unoriented compression molded films. Static room temperature two‐dimensional wide angle X‐ray scattering and Fourier transform infrared spectroscopy were used for phase identification. Differential scanning calorimetry, polarizing optical microscopy, dynamic mechanical analysis (DMA), and thermogravimetic analysis (TGA) were used to study the thermal and mechanical properties. Incorporation of MWCNT into PVDF has no obvious effect in forming beta phase crystal in the PVDF/MWCNT bulk films, while zone drawing cause a significant alpha to beta transition in PVDF/MWCNT. Results indicate that MWCNTs act as nucleation agent during crystallization and slightly increase the degree of crystallinity of PVDF/MWCNT bulk films. TGA indicates the thermal stability is improved when MWCNT concentration increases for unoriented PVDF/MWCNT film. The modulus also increases significantly when MWCNT concentration increases. The glass transition temperature measured by the peak position of tanδ from DMA does not change with MWCNT concentration, but a slightly higher glass transition can be obtained by zone drawing. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010