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Synthesis of thermoreactive polysiloxanes with cyclic fragments in the side chain
Author(s) -
Mukbaniani Omari,
Tatrishvili Tamara,
Titvinidze Giorgi,
Patsatsia Sopho
Publication year - 2009
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.30530
Subject(s) - hydrosilylation , cyclohexene , gel permeation chromatography , polymer chemistry , thermogravimetric analysis , chemistry , platinum , fourier transform infrared spectroscopy , catalysis , copolymer , organic chemistry , polymer , chemical engineering , engineering
The synthesis of polysiloxanes with pendant unsaturated cyclic fragments have been successfully performed by hydrosilylation reactions of polymethylhydrosiloxane with 4‐vinyl‐1‐cyclohexene in the presence of platinum hydrochloric acid (0.1 M solution in THF), Karstedt's catalyst (Pt 2 [(VinSiMe 2 ) 2 O] 3 ) and platinum on the charcoal (5%). Reactions were carried out at various temperatures with different ratios of initial compounds. It was shown, that not all active ≡SiH groups take part in the hydrosilylation reaction. Some kinetic parameters of reactions were studied. The synthesized oligomers were characterized by FTIR, 1 H, 13 C, H,H‐COSY, and C,H‐correlation NMR spectroscopy. Calculations using the quantum‐chemical semi empirical AM1 method for modeling reactions between methyldimethoxysilane [Me(MeO) 2 SiH] and 4‐vinyl‐1‐cyclohexene were performed to evaluate possible reaction paths. Synthesized oligomers were characterized by gel‐permeation chromatography, differential scanning calorimetric, thermogravimetric, and wide‐angle X‐ray analyses. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009