Simultaneous radiation grafting of vinylbenzyl chloride onto poly(tetrafluoroethylene‐ co ‐hexafluoropropylene) films | Zendy

Shin Junhwa | Zendy; Fei Geng | Zendy; Kang SungA | Zendy; Ko BeomSeok | Zendy; Kang PhilHyun | Zendy; Nho Young Chang | Zendy

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Simultaneous radiation grafting of vinylbenzyl chloride onto poly(tetrafluoroethylene‐ co ‐hexafluoropropylene) films

Author(s) -

Shin Junhwa,

Fei Geng,

Kang SungA,

Ko BeomSeok,

Kang PhilHyun,

Nho Young Chang

Publication year - 2009

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.30264

Subject(s) - tetrafluoroethylene , hexafluoropropylene , grafting , monomer , materials science , polymer chemistry , solvent , fourier transform infrared spectroscopy , irradiation , chloride , chemical engineering , nuclear chemistry , copolymer , chemistry , polymer , organic chemistry , composite material , nuclear physics , metallurgy , physics , engineering

In this study, we demonstrated that vinylbenzyl chloride (VBC), a versatile monomer with reactive a chloromethyl group could be grafted onto a poly(tetrafluoroethylene‐ co ‐hexafluoropropylene) (FEP) film without a degradation of the chloromethyl group during a simultaneous irradiation process. The effects of various irradiation conditions such as the total dose, dose rate, solvent, and VBC concentration on the degree of grafting of VBC onto a FEP film were also investigated. The prepared PVBC‐grafted films were characterized using FTIR, TGA, and SEM EDX. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009

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