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Fabrication and characterization of solution cast MWNTs/PEI nanocomposites
Author(s) -
Shao Lu,
Bai YongPing,
Huang Xu,
Meng LingHui,
Ma Jun
Publication year - 2009
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.30197
Subject(s) - polyetherimide , materials science , nanocomposite , carbon nanotube , differential scanning calorimetry , dispersion (optics) , composite material , glass transition , polymer , surface energy , chemical engineering , fourier transform infrared spectroscopy , casting , x ray photoelectron spectroscopy , surface modification , physics , optics , thermodynamics , engineering
Under mild conditions with the aid of ultrasonic, multi‐walled carbon nanotubes (MWNTs) have been functionalized by mixed acid treatment which was proved by FTIR and XPS. According to SEM, acid treatment on MWNTs decreased the thickness of the membrane. However, no devastating damage and fracture happened on MWNTs after acid treatment under mild conditions. Precipitation observation illustrated that the enhanced solubility of MWNTs in water, ethanol, and dimethylformaide (DMF). Further, MWNTs/polyetherimide (PEI) nanocomposite films have been prepared by the simple solution casting method. The dispersion of MWNTs in polyetherimide (PEI) matrix was observed by Atomic Force Microscopy (AFM) which illustrated the improved dispersion for acid treated MWNTs in PEI. The adding of MWNTs in PEI decreased the dispersive component of surface energy and increased the polar component of surface energy, which resulted in the decrement of film surface energy. Differential scanning calorimetry showed that the glass transition temperature of PEI increased by about 4°C after the introduction of MWNTs. This improvement was related to the better affinity between MWNTs and PEI matrix, which also resulted in the improvement of mechanical strength in MWNTs/PEI nanocomposites. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009