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Selective particle distribution and mechanical properties of nano‐CaCO 3 /ethylene‐propylene‐diene terpolymer/polypropylene composites with high content of nano‐CaCO 3
Author(s) -
Wang Xu,
Xu KeJie,
Xu XiangBin,
Park SooJin,
Kim Seok
Publication year - 2009
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.30078
Subject(s) - materials science , polypropylene , composite material , nano , composite number , compounding , nanocomposite , ethylene propylene rubber , izod impact strength test , scanning electron microscope , copolymer , polymer , ultimate tensile strength
T ernary composite of nano‐CaCO 3 /ethylene‐propylene‐diene terpolymer (EPDM)/polypropylene (PP) with high content of nano‐CaCO 3 was prepared by two step compounding route, in which EPDM and nano‐CaCO 3 were mixed first, and then melt compounding with PP matrix. The influence of mixing time during the second compounding on distribution of nano‐CaCO 3 particles and the impact strength of the ternary composite have been investigated. It was found that the Izod impact strength of composite decreased with increasing mixing time. The observation of transmission electron microscopy obviously showed that nano‐CaCO 3 particles transported from EPDM to PP matrix firstly and then from PP to the vicinity of EPDM dispersed phase with the increase of mixing time. This phenomenon can be well explained by the minimization of the dissipative energy and the Young's equation. The scanning electron microscope images show that lots of nano fibrils exist at the interface between nano‐CaCO 3 agglomerates and matrix, which can dissipate lots of energy. The toughening mechanism has been interpreted in terms of three‐stage‐mechanism: stress concentration, void and shear band formation, and induced shear yielding. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009