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Investigation on the fracture behavior and morphology of maleated poly(ethylene 1‐octene) toughened and glass fiber‐reinforced nylon 1010
Author(s) -
Yu Haiyang,
Zhang Yong,
Ren Wentan
Publication year - 2009
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.29531
Subject(s) - materials science , composite material , octene , toughness , nylon 6 , fracture toughness , fiber , glass fiber , polymer , copolymer
Abstract The maleated poly(ethylene 1‐octene) (POE‐ g ‐MAH)‐toughened and glass fiber (GF)‐reinforced nylon 1010 was prepared by melting extrusion. A good trade‐off between stiffness and toughness was obtained by the combination of POE‐ g ‐MAH and GF. The essential work of fracture (EWF) model was used to characterize the fracture behavior of nylon/POE‐ g ‐MAH/GF composites. With increasing GF content, the energy consumed in outer plastic zone gradually decreased, and the work consumed in inner fracture process zone reached the maximum value at the GF content of 10 wt %. Morphology investigations showed that POE‐ g ‐MAH was uniformly dispersed in nylon/POE‐ g ‐MAH (80/20) blend, and the nylon around POE‐ g ‐MAH particles suffered a great plastic deformation in the impact test. For nylon/POE‐ g ‐MAH/GF composites, large plastic deformation occurred in the matrix around GF rather than around rubber particles. Dynamic mechanical analysis showed that GF significantly increased the storage and loss moduli and decreased value of tan δ, but had little effect on its position. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009