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Improving the creep stability of high‐density polyethylene with acicular titania nanoparticles
Author(s) -
Bondioli F.,
Dorigato A.,
Fabbri P.,
Messori M.,
Pegoretti A.
Publication year - 2009
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.29472
Subject(s) - high density polyethylene , materials science , acicular , creep , composite material , nanoparticle , polyethylene , nanocomposite , ultimate tensile strength , compounding , elastic modulus , crystallization , chemical engineering , microstructure , nanotechnology , engineering
Acicular titania nanoparticles with average dimensions of 15 × 60 nm 2 were produced by hydrothermal crystallization of TiOCl 2 . Titania particles were surface‐functionalized with octadecylsilane to obtain an organophilic surface. High‐density polyethylene (HDPE) nanocomposites were prepared by melt compounding with 2, 3, and 5 vol % concentrations of untreated and surface‐functionalized titania nanoparticles. Quasi‐static mechanical tensile tests evidenced slight increments of both the elastic modulus and stress at yield, which were accompanied by a marked reduction of the strain at break at high filler contents. The introduction of titania nanoparticles induced a substantial reduction of the creep compliance of the HDPE matrix and of its creep rate, especially at long loading times. Untreated titania nanoparticles were more effective in reducing the creep compliance than the functionalized ones. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009