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A comparison of the properties of rice husk ash, silica, and calcium carbonate filled 75 : 25 NR/EPDM blends
Author(s) -
Arayapranee Wanvimon,
Rempel Garry L.
Publication year - 2008
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.28725
Subject(s) - materials science , vulcanization , natural rubber , composite material , tear resistance , ultimate tensile strength , precipitated silica , calcium carbonate , curing (chemistry) , filler (materials) , husk , elastomer , epdm rubber , polymer blend , polymer , copolymer , botany , biology
The effects of incorporation of three different fillers, i.e., rice husk ash (RHA), silica, and calcium carbonate (CaCO 3 ), over a loading range of 0–60 phr on the curing characteristics, processability, mechanical properties, and morphology of 75 : 25 natural rubber (NR)/ethylene‐propylene‐diene monomer (EPDM) blends were studied using a conventional vulcanization system. Filler loading and type influence the processability of the blends in which RHA and CaCO 3 offer better processing advantage over silica. The best improvement in the tensile and tear strength and abrasion resistance of the 75 : 25 NR/EPDM blends with additional fillers was achieved when filled with silica. However, RHA and CaCO 3 were better in resilience property compared to that of silica. The RHA filled blends showed higher failure properties and abrasion resistance but lower ozone resistance than that containing CaCO 3 . Scanning electron micrographs revealed that the morphology of the blend filled with silica is finer and more homogenous compared to the blend filled with RHA and CaCO 3 . According to these observations, RHA can be used as a cheaper filler to replace CaCO 3 in rubber blends where improved mechanical properties are not so critical. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008