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Catalytic performance of cellulose supported palladium complex for Heck reaction in water
Author(s) -
Xu Ying,
Zhang Lei,
Cui Yuanchen
Publication year - 2008
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.28655
Subject(s) - catalysis , palladium , cellulose , acrylic acid , aryl , heck reaction , polymer chemistry , styrene , x ray photoelectron spectroscopy , chemistry , reusability , organic chemistry , materials science , copolymer , chemical engineering , polymer , alkyl , software , computer science , engineering , programming language
Cellulose supported palladium complex was synthesized and characterized by XPS, TG/DTA etc. The complex was found to be an efficient catalyst for Heck reaction of acrylic acid or styrene with aryl iodides at low temperature in water under atmospheric condition, the substituted trans ‐cinnamic acid or 1,2‐stilbene was obtained in stereoselectivity. Repeated tests showed that the catalyst have good reusability. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008