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Association and effective hydrodynamic thickness of hydrophobically associating polyacrylamide through porous media
Author(s) -
Lu Hongsheng,
Feng Yujun,
Huang Zhiyu
Publication year - 2008
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.28596
Subject(s) - polyacrylamide , materials science , shear thinning , porous medium , porosity , polymer , shear (geology) , dilatant , chemical engineering , rheology , composite material , polymer chemistry , engineering
This study was aimed at the association and effective hydrodynamic thickness of hydrophobically associating polyacrylamide (HAPAM) through porous media with coreflow experiment. It shows that there is strong hydrophobic association for HAPAM in porous media but not for polyacrylamide (PAM). The resistance factor and effective hydrodynamic thickness of HAPAM are obviously superior to those of PAM. HAPAM exhibits much stronger shear thinning behavior than PAM due to the ability to form transitional network structure. It also indicates that PAM can exhibit a transition from shear thinning behavior to shear thickening behavior at low polymer concentration. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008