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Effects of blend composition and dynamic vulcanization on the morphology and dynamic viscoelastic properties of PP/EPDM blends
Author(s) -
Prut E.V.,
Eri.A.,
KargerKocsis J.,
Medintseva T.I.
Publication year - 2008
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.28158
Subject(s) - materials science , vulcanization , composite material , viscoelasticity , rheology , thermoplastic elastomer , elastomer , polymer blend , polypropylene , dynamic mechanical analysis , thermoplastic , epdm rubber , ethylene propylene rubber , rheometer , tacticity , natural rubber , copolymer , polymer , polymerization
The morphology and dynamic viscoelastic properties of isotactic polypropylene (PP) blended with oil‐free/oil‐extended ethylene–propylene–diene (EPDM) rubbers were studied. Unvulcanized and dynamically vulcanized blends with the compositions PP/EPDM = 50/50 and = 30/70 were investigated. The morphology was observed by phase contrasted atomic force microscopy. The dynamic viscoelastic properties were determined with a rheometer of plate–plate configuration. It was shown that the rheological behavior was strongly affected by both the composition and the morphology of the blends. Significant improvement in the flowability of the dynamically vulcanized blends was observed when oil‐extended EPDM was used instead of the oil‐free version. It was demonstrated that the rheological properties are mostly controlled by the elastomer phase at low frequencies, while in the high‐frequency range the influence of PP becomes dominant. The peculiarities in the rheological behavior of the thermoplastic elastomers (uncured blends, TPE) and thermoplastic dynamic vulcanizates (TPV, dynamically cured blends) containing oil‐extended EPDMs were traced to a limited compatibility between the PP and EPDM components in the melt. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008