Grafting polymer from poly(ethylene terephthalate) films by surface‐initiated ATRP | Zendy

Zhang Hongwen | Zendy; Shouro Daisuke | Zendy; Itoh Koichi | Zendy; Takata Tadahiko | Zendy; Jiang Yan | Zendy

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Grafting polymer from poly(ethylene terephthalate) films by surface‐initiated ATRP

Author(s) -

Zhang Hongwen,

Shouro Daisuke,

Itoh Koichi,

Takata Tadahiko,

Jiang Yan

Publication year - 2007

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.27619

Subject(s) - materials science , atom transfer radical polymerization , x ray photoelectron spectroscopy , copolymer , polymer chemistry , polymer , grafting , contact angle , ethylene , methyl methacrylate , methacrylate , polymerization , chemical engineering , composite material , chemistry , organic chemistry , catalysis , engineering

Surface‐initiated atom transfer radical polymerization (ATRP) from poly(ethylene terephthalate) (PET) film was studied. Poly(methyl methacrylate) (PMMA), poly (acrylamide) (PAAM), and their diblock copolymer (PMMA/PAAM) on the surface of PET film were successfully prepared by surface‐initiated ATRP. The structures and properties of the modified PET film were characterized by FT‐IR/ATR, X‐ray photoelectron spectroscopy (XPS), measurements of contact angles, and scanning electronic microscopy (SEM). The results indicate that the surface properties of PET film were greatly improved by grafted polymer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008

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