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Optimization of synthesis conditions of a novel carrageenan‐based superabsorbent hydrogel by Taguchi method and investigation of its metal ions adsorption
Author(s) -
Pourjavadi A.,
AminiFazl M. S.,
Barzegar Sh.
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.27466
Subject(s) - taguchi methods , ammonium persulfate , superabsorbent polymer , monomer , materials science , adsorption , self healing hydrogels , chemical engineering , metal ions in aqueous solution , fourier transform infrared spectroscopy , acrylic acid , polymer chemistry , biopolymer , nuclear chemistry , chemistry , metal , polymer , composite material , organic chemistry , engineering , metallurgy
The Taguchi method, a robust experimental design, was used for optimization of synthesis of a novel biopolymer‐based superabsorbent hydrogel, kappa‐carrageenan (κ‐C)‐ g ‐acrylic acid (AA)‐ co ‐2‐acrylamido‐2‐methylpropanesulfonic acid (AMPS). The Taguchi method was applied for the experimental and standard 18 orthogonal arrays (OA) with seven factors and three levels for each factor. In the synthesis of the superabsorbent, N,N '‐methylene bisacrylamide (MBA) as crosslinker, ammonium persulfate (APS) as initiator, monomer ratio (AA/AMPS), κ‐C concentration, Total Monomer, neutralization percent (NU), and reaction temperature were used as important factors. After analyzing with analysis of variance (ANOVA) results showed that maximum water absorption capability for optimized final product was found to be 1195 g water per one gram of dry hydrogel powder. The proposed mechanism for the grafting and chemically crosslinking reactions was proved with FTIR, SEM, and TGA methods. Furthermore, the absorption capability of the hydrogels towards bivalent metal ions was evaluated. Therefore, the hydrogels may be based‐considered as a candidate to develop an efficient biofilm absorbent in water treatment applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008