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Photo and thermal polymerization of epoxides and vinyl ethers by novel sulfonium salts
Author(s) -
Kim Jun Young,
Patil Prashant S.,
Seo Byoung Jun,
Kim Tae Soo,
Kim Jinhwan,
Kim Tae Ho
Publication year - 2008
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.27333
Subject(s) - sulfonium , polymerization , polymer chemistry , monomer , nucleophile , vinyl ether , chemistry , ether , materials science , organic chemistry , polymer , catalysis , salt (chemistry)
Novel Sulfonium salts with non‐nucleophilic anions were synthesized and applicability of these salts as initiators was demonstrated by carried out polymerization (photo and thermal) of epoxides as well as vinyl ether monomers. Newly synthesized initiators showed good activity for the photo and thermal polymerization. Synthesis, characterization, and activity of initiators have been described. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008.