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Hydroxyalkylation of barbituric acid. II. Synthesis of polyetherols with pyrimidine ring
Author(s) -
Ślączka Anna,
Lubczak Jacek
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.26742
Subject(s) - barbituric acid , pyrimidine , hydroxymethyl , ring (chemistry) , polymer chemistry , polyurethane , thermal stability , ethylene , chemistry , derivative (finance) , materials science , organic chemistry , stereochemistry , catalysis , financial economics , economics
The route of synthesis of new polyetherols with pyrimidine ring from barbituric acid (BA) was presented. The polyetherols were obtained in two steps: synthesis of hydroxymethyl derivative of BA followed by reaction of the latter with neat ethylene or propylene oxides. Physical properties of the products and preliminary application for fabrication of thermal stability polyurethane foams were determined. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007