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Metal ion interaction of water‐soluble copolymers containing carboxylic acid groups in aqueous phase by membrane filtration technique
Author(s) -
Pizarro Guadalupe Del C.,
Marambio Oscar G.,
JeriaOrell Manuel,
Huerta Margarita R.,
Rodríguez Oscar O.,
Rivas Bernabé L.,
Geckeler Kurt E.
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.26467
Subject(s) - copolymer , polymer chemistry , differential scanning calorimetry , dispersity , aqueous solution , metal ions in aqueous solution , polymer , thermogravimetry , metal , materials science , chemistry , inorganic chemistry , organic chemistry , physics , thermodynamics
This article reports the synthesis of poly( N ‐maleoylglycine‐ co ‐itaconic acid) by radical copolymerization under different feed mole ratios and its properties to remove various metal ions, such as Cu(II), Cr(III), Co(II), Zn(II), Ni(II), Pb(II), Cd(II), and Fe(III), in aqueous phase with the liquid‐phase polymer‐based retention(LPR) technique. The interactions of inorganic ions with the hydrophilic water‐soluble polymer were determined as a function of pH and filtration factor. Metal ion retention was found to strongly depend on the pH. Metal ion retention increased as pH and MG content units in the macromolecular backbone increased. The copolymers were characterized by elemental analysis, FTIR, 1 H‐NMR, and 13 C‐NMR spectroscopy. Additionally, intrinsic viscosity, molecular weight, and polydispersity have been determined for the copolymers. Copolymer and polymer–metal complex thermal behavior was studied using differential scanning calorimetry (DSC) and thermogravimetry (TG) techniques under nitrogen atmosphere. The thermal decomposition temperatures (TDT) were influenced by the copolymer composition. The copolymers present lower TDT than the polymer–metal complex with the same copolymer composition. All copolymers present a single T g , indicating the formation of random copolymers. A slight deviation of the T g for the copolymers and its complexes can be observed. The copolymer T g is higher than the T g value for the polymer–metal complexes. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007