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Synthesis and thermal behavior of some anthracene‐based copolymers obtained by Diels–Alder cycloaddition reactions
Author(s) -
Grigoras M.,
Sava M.,
Colotin G.,
Simionescu C. I.
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.26466
Subject(s) - cycloaddition , anthracene , thermogravimetric analysis , copolymer , monomer , polymer chemistry , polymer , diels–alder reaction , materials science , fourier transform infrared spectroscopy , chemistry , organic chemistry , chemical engineering , composite material , catalysis , engineering
New polymer structures have been synthesized via Diels–Alder cycloaddition of bisdiene compounds bearing two anthracene groups and different bisdienophiles, all containing bismaleimide or biscitraconimide functions. The monomers and polymers were characterized by FTIR, UV, and 1 H NMR techniques and compared with two models having a cycloadduct structure. The polymers were studied by thermogravimetric analyses. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008