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The influence of latex blend composition on crosslinking and mechanical properties
Author(s) -
Boyars Brian,
Daniels Eric S.,
Storer Robert,
Klein Andrew
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.25947
Subject(s) - materials science , swelling , copolymer , methacrylate , emulsion , polymer , composite material , dynamic mechanical analysis , polymer chemistry , chemical engineering , engineering
Model reactive latices were synthesized by semicontinuous emulsion copolymerization of n ‐butyl methacrylate and acetoacetoxyethyl methacrylate or dimethylaminoethyl methacrylate. The two functional latices were then blended in various ratios to study the influence of blend composition on crosslinking and mechanical properties of the resulting films. Crosslinking was quantified through swelling measurements. It was found that the crosslink density increased with increasing amounts of acetoacetoxy‐functional polymer. In addition, the crosslink density exhibited two maxima, at 30/70 and 70/30 (acetoacetoxy‐functional latex/amino‐functional latex) blend compositions. The mechanical properties of the films were quantified by dynamic mechanical analysis (DMA). It was shown that optimal mechanical properties occurred when the particles packed most efficiently at the 30/70 and 70/30 blend compositions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 3774–3779, 2007