Premium
Reinforcement of the interface in drawn polymer blends PS/PA‐12
Author(s) -
Miroshnikov Y. P.,
Chaves G. A.,
Vlasov S. V.,
Gerasimov V. I.
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.25849
Subject(s) - materials science , polystyrene , phase (matter) , miscibility , dispersion (optics) , viscosity , polymer blend , plasticizer , composite material , polymer , reinforcement , polymer chemistry , chemical engineering , chemistry , copolymer , organic chemistry , physics , optics , engineering
The origin of the reinforcement effect in uniaxially drawn films on the basis of immiscible blends composed of crystalline matrix of polyamide‐12 (PA) and glassy polystyrene (PS) dispersed phase has been investigated. Other conditions being equal, the effect becomes the more pronounced the lager the draw ratio and the finer the PS dispersion. Since the latter factor is itself a strong function of phase viscosity ratio (μ), the following two techniques of adjusting the optimal value of μ ≈ 1 have been adopted. According to the first one, a selective plasticizer, which is a good solvent for the PS minor phase and a nonsolvent for the PA matrix phase, was added to the more viscous PS. According to the second approach, the value of μ was varied by the use of PS samples of different molecular weights. It was shown that significant reinforcement effect appears on drawing regardless of the method of adjusting optimal phase viscosity ratio. These data as well as the results obtained with the help of IR‐dichroism and transmission electron microscopy techniques evidence that the formation of a much more ordered crystalline morphology of the PA matrix located at the PS/PA interfaces and a large interface area are mainly responsible for the discussed reinforcement phenomenon. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1299–1305, 2007