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Use of polymeric nitrosation reagents for the N‐nitrosation of secondary amines under mild and heterogeneous conditions
Author(s) -
Zarchi M. A. Karimi,
Noei J.
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.25487
Subject(s) - nitrosation , reagent , chemistry , nitrite , polymer chemistry , sodium nitrite , chloride , organic chemistry , nitrate
A combination of crosslinked poly(4‐vinylpyridinium)chloride [P 4 ‐H]Cl ( I ) and sodium nitrite or quaternized crosslinked poly( N ‐methyl‐4‐vinylpyridinium)nitrite [P 4 ‐Me]NO 2 ( II ) was used as effective nitrosating agents for the N‐nitrosation of secondary amines under mild and heterogeneous conditions in moderate to excellent yields. The spent polymeric reagents can usually be removed quantitatively and regenerated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1064–1067, 2007