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Thermal conductivity of carbon fiber/liquid crystal polymer composites
Author(s) -
Keith Jason M.,
King Julia A.,
Miller Michael G.,
Tomson Amanda M.
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.25102
Subject(s) - thermal conductivity , materials science , composite material , polyacrylonitrile , volume fraction , graphite , thermosetting polymer , conductivity , fiber , thermal conduction , polymer , chemistry
Thermally conductive resins are needed for bipolar plates in fuel cells. Currently, the materials used for these bipolar plates often contain a single type of graphite in a thermosetting resin. In this study, varying amounts of two different types of polyacrylonitrile based carbon fibers, Fortafil 243 and Panex 30, were added to a thermoplastic matrix (Vectra A950RX Liquid Crystal Polymer). The resulting single filler composites were tested for thermal conductivity and a simple exponential thermal conductivity model was developed for the square root of the product of the in‐plane and through‐plane thermal conductivity $\sqrt{k_{\rm in}k_{\rm thru}}$ . The experiments showed that the through‐plane thermal conductivity was similar for composites up to 40 vol % fiber. However, at higher loadings, the Panex 30 samples exhibited higher thermal conductivity. The experiments also showed that the in‐plane thermal conductivity of composites containing Panex 30 was higher than those containing Fortafil 243 for all volume fractions studied. Finally, the model agreed very well with experimental data covering a large range of filler volume fraction (from 0 to 55 vol % for both single filler systems). The model can be used with existing through‐plane thermal conductivity models to predict in‐plane thermal conductivity. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5456–5462, 2006