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Effect of ATH content on electrical and aging properties of EVA and silicone rubber blends for high voltage insulator compound
Author(s) -
Pradeep M. A.,
Vasudev N.,
Reddy P. V.,
Khastgir D.
Publication year - 2007
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.24944
Subject(s) - materials science , composite material , silicone rubber , polydimethylsiloxane , ethylene vinyl acetate , electrical resistivity and conductivity , natural rubber , absorption of water , silicone , copolymer , polymer chemistry , polymer , electrical engineering , engineering
The effect of trihydrated alumina (Al 2 O 3 , 3H 2 O) (ATH) filler in ethylene‐vinyl acetate copolymer (EVA) and silicone rubber blends was investigated by performing a series of laboratory experiments to simulate different natural aging conditions. Samples with varying ATH content in a 50‐50 blend of EVA and polydimethylsiloxane (PDMS) (silicone rubber, MQ) were tested to investigate the tracking resistance, resistance to UV radiation, corona, heat, and water immersion. Changes in surface resistivity, volume resistivity, and hydrophobic characteristics were evaluated for different compounds having ATH content. These exercises were mainly carried out to optimize the filler level. In immersed condition the water absorption increases with ATH content. The recovery of hydrophobicity, after aging by heat, is appreciable at higher ATH levels, than at lower ATH levels. The tracking and erosion resistance decrease as ATH content increases. When compounds containing different ATH content were subjected to corona treatment, the samples with higher ATH levels exhibited better results. All samples changed their color to a darker shade and there was an increase in the hydrophobicity, when subjected to UV radiation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 3505–3516, 2007