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Preparation of magnetic poly(glycidyl methacrylate) microspheres by emulsion polymerization in the presence of sterically stabilized iron oxide nanoparticles
Author(s) -
Horák Daniel,
Chekitaliya
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.24923
Subject(s) - glycidyl methacrylate , emulsion polymerization , ammonium persulfate , polymer chemistry , emulsion , dextran , materials science , methacrylate , polymerization , nanoparticle , chemical engineering , nuclear chemistry , chemistry , polymer , organic chemistry , nanotechnology , composite material , engineering
With the aim to synthesize water‐dispersible superparamagnetic nanoparticles, iron oxide was precipitated in aqueous solution of dextran, (carboxymethyl) dextran (CM‐dextran), (DEAE‐dextran), or D ‐mannose. Glycidyl methacrylate (GMA) was emulsion‐polymerized in the presence of the nanoparticles and the effect of iron oxide modification on the product properties was investigated. The main factors affecting the morphology, size, and size distribution of the latex particles are the type and concentration of emulsifier (Disponil AES 60, Tween 20, Triton X‐100) and initiator [ammonium persulfate (APS) and 4,4′‐azobis(4‐cyanovaleric acid) (ACVA)]. Disponil AES 60 and ACVA are the preferred emulsifier and initiator, respectively, because oxirane groups hydrolyzed during the APS‐initiated polymerization. Up to some 5 wt % of iron was found in poly(glycidyl methacrylate) (PGMA) microspheres obtained by emulsion polymerization in the presence of dextran‐coated iron oxide and emulsified with Disponil AES 60. The size of magnetic PGMA microspheres could be controlled in the range ˜ 70–400 nm. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4348–4357, 2006