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Improving rheological property of polymer melt via low frequency melt vibration
Author(s) -
Li Youbing,
Shen Kaizhi,
Zhan Jie
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.24791
Subject(s) - extrusion , rheology , materials science , composite material , crystallinity , polymer , amorphous solid , shear thinning , high density polyethylene , vibration , melt flow index , viscosity , polyethylene , chemistry , copolymer , acoustics , physics , organic chemistry
A pulse pressure was superimposed on the melt flow in extrusion, called vibration extrusion. A die ( L/D = 17.5) was attached to this device to study the rheological properties of an amorphous polymer (ABS) and semicrystalline polymer (PP, HDPE), prepared in the vibration field, and the conventional extrusion were studied for comparison. Results show that the melt vibration technique is an effective processing tool for improving the polymer melt flow behavior for both crystalline and amorphous polymers. The enhanced melt rheological property is also explained in terms of shear thinning criteria. Increasing with vibration frequency, extruded at constant vibration pressure amplitude, the viscosity decreases sharply, and so does when increasing vibration pressure amplitude at a constant vibrational frequency. The effect of vibrational field on melt rheological behavior depends greatly on the melt temperature, and the great decrease in viscosity is obtained at low temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5292–5296, 2006