Premium
Effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents
Author(s) -
Cheng Shaoling,
Tang Haiyan,
Yan Husheng
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.24702
Subject(s) - adsorption , hydrogen bond , chemistry , resorcinol , polystyrene , hydrophobic effect , phenol , polymer chemistry , molecule , organic chemistry , polymer
Abstract To investigate the effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents, macroporous polystyrene (PS) resin and PS‐based adsorbents with different hydrogen‐bond acceptor atoms (PSCH 2 (OCH 2 CH 2 ) n OCH 3 , n = 0, 1, 2, and 3, denoted as PS‐EG 0 , PS‐EG 1 , PS‐EG 2 , and PS‐EG 3 ) were prepared. The phenol adsorption strength order on these adsorbents was PS/PS‐EG 0 < PS‐EG 1 < PS‐EG 2 < PS‐EG 3 , indicating that the adsorption on PS and PS‐EG 0 was driven by hydrophobic and π–π interactions, and the adsorption on PS‐EG 1 , PS‐EG 2 , and PS‐EG 3 was driven by a hydrogen bond in addition to hydrophobic and π–π interactions. PS‐EG 2 may adsorb a second phenol molecule on each binding site and PS‐EG 3 may adsorb second and third ones. The adsorption strength of resorcinol increased in the order of PS, PS‐EG 1 , and PS‐EG 2 , indicating that the adsorption was driven by 0, 1, and 2 hydrogen bonds in addition to hydrophobic and π–π interactions. Similarly, the adsorption of phloroglucinol on PS, PS‐EG 1 , PS‐EG 2 , and PS‐EG 3 was driven by 0, 1, 2, and 3 hydrogen bonds in addition to hydrophobic and π–π interactions because the adsorption strength increased in this order. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4652–4658, 2006