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Synthesis of poly(epichlorohydrin‐ g ‐methyl methacrylate) graft copolymers by the combination of cationic and atom transfer radical polymerization
Author(s) -
Cakmak Ismail,
Baykara Haci
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.24301
Subject(s) - epichlorohydrin , atom transfer radical polymerization , polymer chemistry , copolymer , cationic polymerization , methyl methacrylate , styrene , gel permeation chromatography , radical polymerization , materials science , photopolymer , methacrylate , polymerization , polymer , chain transfer , chemistry , organic chemistry
Poly(epichlorohydrin) possessing chloromethyl side groups in the main chain was used in the atom transfer radical polymerization of methyl methacrylate and styrene to yield poly(epichlorohydrin‐ g ‐methyl methacrylate) and poly(epichlorohydrin‐ g ‐styrene graft copolymers. The polymers were characterized by 1 H NMR spectroscopy, gel permeation chromatography, differential scanning calorimetry, and fractional precipitation method. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 2725–2729, 2006