Characterization of sulfonated poly(styrene–divinylbenzene) and poly(divinylbenzene) and its application as catalysts in esterification reaction | Zendy

Coutinho Fernanda M. B. | Zendy; Rezende Simone M. | Zendy; Soares Bluma G. | Zendy

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Characterization of sulfonated poly(styrene–divinylbenzene) and poly(divinylbenzene) and its application as catalysts in esterification reaction

Author(s) -

Coutinho Fernanda M. B.,

Rezende Simone M.,

Soares Bluma G.

Publication year - 2006

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.24046

Subject(s) - divinylbenzene , styrene , monomer , toluene , sulfuric acid , acetic acid , catalysis , polymer chemistry , suspension polymerization , materials science , polymerization , heptane , diluent , chemistry , organic chemistry , polymer , copolymer

Polymeric supports based on divinylbenzene (DVB) were prepared by aqueous suspension polymerization in presence or absence of styrene (S), using toluene and n ‐heptane as diluents of the monomers. Poly(S–DVB) and poly(DVB) were sulfonated with sulfuric acid in presence of 1,2‐dichloroethane. The influence of the morphological structure of the supports and as a consequence of the catalyst on the esterification reaction of acetic acid with n ‐butanol was evaluated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3616–3627, 2006

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