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Reactions of copper ions with amines in the presence of self‐assembled fluorinated oligomeric aggregates
Author(s) -
Sawada Hideo,
Furukuwa Rika,
Sasazawa Kazuo,
Toriba KenIchi,
Ueno Katsuya,
Hamazaki Kazuo
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.23787
Subject(s) - copper , polymer chemistry , methacrylate , nanocomposite , methyl methacrylate , chemistry , hydrate , materials science , polymer , organic chemistry , copolymer , nanotechnology
Abstract Copper acetylacetonate reacted with N , N ‐diethylmethylamine and 4,4′‐thiobis(6‐ t ‐butyl‐ o ‐cresol) in the presence of self‐assembled fluorinated oligmeric aggregates formed by fluoroalkyl end‐capped 2‐[3‐(2H‐benzotriazol‐2‐yl)‐4‐hydroxyphenyl]ethyl methacrylate– N , N ‐dimethylacrylamide cooligomer [R F –(BTRI) x –(DMAA) y –R F ; R F = CF(CF 3 )OCF 2 CF(CF 3 )OC 3 F 7 ] to afford stable fluorinated aggregates–copper ions nanocomposites. These fluorinated oligomeric aggregates–copper ions nanocomposites thus obtained were applied to the dispersion of copper ions nanocomposites above the traditional organic polymeric materials such as poly(methyl methacrylate) (PMMA) surface. On the other hand, copper (II) chloride reacted with hydrazine hydrate in the presence of fluorinated oligomeric aggregates formed by fluoroalkyl end‐capped N , N ‐dimethylacrylamide homooligomer to afford stable copper nanoparticles. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1328–1334, 2006